DOI: 10.1055/b-00000091

Methoden der Organischen Chemie (Houben-Weyl)

DOI: 10.1055/b-003-113756 Online ISBN 9783131939715
Helmchen, Günter; Hoffmann, Reinhard W.; Mulzer, Johann; et al.: 1995

Stereoselective Synthesis

C—C Bond Formation by Sigmatropic Rearrangements, Electrocyclic Reactions, C—H, C—Hal Bond Formation Print ISBN 9783131001146 · Online ISBN 9783131969842
Volume: E 21 d
More Information

Book

Editors: Helmchen, Günter; Hoffmann, Reinhard W.; Mulzer, Johann; Schaumann, Ernst

Authors: Bohlmann, R.; Brown, J. M.; Brunner, H.; Davis, A. P.; Khawaga, A. M. EL; Frauenrath, H.; Giese, B.; Ghosez, A.; Göbel, T.; Gottwald, M.; Hasselmann, D.; Hoffmann, H. M. R.; Hünig, S.; Kallmerten, J.; Kazmaier, U.; Krohn, K.; Leuenberger, H.G.W.; Martens, J.; Matzinger, P. K.; Midland, M. M.; Morell, L. A.; Pelter, L.; Pfaltz, A.; Takacs, J. M.; Zaidlewicz, M.; Zipse, H.

Title: Stereoselective Synthesis

Subtitle: C—C Bond Formation by Sigmatropic Rearrangements, Electrocyclic Reactions, C—H, C—Hal Bond Formation

Print ISBN: 9783131001146; Online ISBN: 9783131969842; Book DOI: 10.1055/b-003-113756

4th Edition © 1995 Georg Thieme Verlag KG
Georg Thieme Verlag KG, Stuttgart

Subjects: Stereoselective Synthesis

Houben-Weyl (Chemistry)



Parent publication

Title: Methoden der Organischen Chemie (Houben-Weyl)

Print ISBN: 9783131400840; Online ISBN: 9783131939715; DOI: 10.1055/b-00000091

Type: Multivolume Edition

Front Matter
Part D. Synthesis of Chiral Compounds by Bond Formation: 1. Formation of C - C Bonds
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (I)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (II)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (III)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (IV)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (V)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (VI)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (VII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (VIII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (IX)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (X)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XI)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XIII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XIV)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XV)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XVI)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XVII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XVIII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XIX)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XX)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XXI)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XXII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XXIII)
1.6. Pericyclic Reactions: 1.6.3 Sigmatropic Rearrangements and Electrocyclic Reactions (XXIV)
Part D. Synthesis of Chiral Compounds by Bond Formation: 2. Formation of C-H Bonds
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.1 Formation of Prostereogenic Carbanions
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.2 Diastereoselective Protonation of Carbanions
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.3 Diastereoselective Protonation of Enolates
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.4 Diastereoselective Protonation of Nitrogen-Containing Anions
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.5 Diastereoselective Protonation of Ketenes by Addition of Chiral Alcohols
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.6 Enantioselective Protonation of Carbanions
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.7 Enantioselective Protonation of Enamines (Deracemization of Carbonyl Compounds)
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.8 Enantioselective Protonation of Enones
2.1.Protonation of Carbanions and Polar Double Bonds: 2.1.9 Enantioselective Protonation of Ketenes by the Addition of Alcohols and Thiols
2.2 Radical Reactions: 2.2.1 Acyc1ic Radicals
2.2 Radical Reactions: 2.2.2 Cyc1ic Radicals
2.3 Reduction of Carbonyl Groups: 2.3.1 Hydrogenation with Molecular Hydrogen
2.3 Reduction of Carbonyl Groups: 2.3.2 Formation of C-H Bonds by the Reduction of C-C Double Bonds and of Carbonyl Groups with Metals ('Dissolving Metal Reduction')
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (I)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (II)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (III)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (VI)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (V)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (VI)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (VII)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (VIII)
2.3 Reduction of Carbonyl Groups: 2.3.3 Formation of C-H Bonds by the Reduction of Carbonyl Groups with Metal Hydrides (XI)
2.4 Reduction of Imino Groups: 2.4.1 Catalytic Hydrogenation and Hydrosilylation
2.4 Reduction of Imino Groups: 2.4.2 Reductions with Complex Hydride Reagents
2.4 Reduction of Imino Groups: 2.4.3 Reductions with Metals
2.4 Reduction of Imino Groups: 2.4.4 C - H Hydride Donors
2.4 Reduction of Imino Groups: 2.4.5 Enzyme-Catalyzed and Biomimetic Reductions
2.4 Reduction of Imino Groups: 2.4.6 Electrochemical Reductions
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (I)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (II)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (III)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (VI)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (V)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (VI)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (VII)
2.5 Reduction of Olefinic Double Bonds 2.5.1 Formation of C-H Bonds by Hydrogenation (VIII)
2.5 Reduction of Olefinic Double Bonds 2.5.2 Formation of C - H Bonds by Reduetion of Olefinic Double Bonds via Hydroboration and Hydroalumination
2.6 [l,n] Sigmatropic Rearrangements 2.6.1 Seope and Limitations
2.6 [l,n] Sigmatropic Rearrangements 2.6.2 Speeifie [l,n] Sigmatropie Hydrogen Shifts (I)
2.6 [l,n] Sigmatropic Rearrangements 2.6.2 Speeifie [l,n] Sigmatropie Hydrogen Shifts (II)
2.6 [l,n] Sigmatropic Rearrangements 2.6.3 Conclusions
Part D. Synthesis of Chiral Compounds by Bond Formation: 3. Formation of C-Hal Bonds
3.1.Halogenation of Alcohols and Alcohol Derivatives: 3.1.1 Fluorination
3.1.Halogenation of Alcohols and Alcohol Derivatives: 3.1.2 Chlorination
3.1.Halogenation of Alcohols and Alcohol Derivatives: 3.1.3 Bromination and Iodination
3.2. Electrophilic Halogenation: 3.2.1 Halogenation of Enols and Enolates
3.2. Electrophilic Halogenation: 3.2.2 Halogenation of Alkenes and Alkynes
3.2. Electrophilic Halogenation: 3.2.3 Haloetherification and Lacton(am)ization
3.2. Electrophilic Halogenation: 3.2.4 Halogenation of Organometallic Compounds
3.2. Electrophilic Halogenation: 3.2.5 Halogenation of Organoboranes
3.2. Electrophilic Halogenation: 3.2.6 Other Halogenations
Annex