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Synfacts 2011(12): 1331-1331
DOI: 10.1055/s-0031-1289326
DOI: 10.1055/s-0031-1289326
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones
F. Xue, X. Li, B. Wan*
Dalian Institute of Chemical Physics, P. R. of China
Further Information
Publication History
Publication Date:
18 November 2011 (online)
Significance
The authors developed a class of chiral olefin-sulfoxide hybrid ligands and utilized them in the Rh-catalyzed asymmetric conjugate addition to attain high yield and enantioselectivity. A benzene ring links the olefin and the sulfoxide, providing suitable coordination to the metal center.