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Synfacts 2006(12): 1264-1264  
DOI: 10.1055/s-2006-949491
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York

Enantioselective Conjugate Radical Addition

Contributor(s): Hisashi Yamamoto, Joshua P. Abell
S. Lee, C. J. Lim, S. Kim*, R. Subramaniam, J. Zimmerman, M. P. Sibi*
Korea Advanced Institute of Sciences and Technology, Daejeon, Korea and , North Dakota State University, Fargo, USA
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Publication History

Publication Date:
22 November 2006 (online)

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Significance

Enantioselective radical reactions have attracted interest lately due to their ability to introduce various stable radical intermediates to electrophiles. This paper reports the radical conjugate addition to enones using a 1,4-chelating template as opposed to the more popular 1,5-chelate.