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Synfacts 2006(12): 1264-1264
DOI: 10.1055/s-2006-949491
DOI: 10.1055/s-2006-949491
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Enantioselective Conjugate Radical Addition
S. Lee, C. J. Lim, S. Kim*, R. Subramaniam, J. Zimmerman, M. P. Sibi*
Korea Advanced Institute of Sciences and Technology, Daejeon, Korea and , North Dakota State University, Fargo, USA
Further Information
Publication History
Publication Date:
22 November 2006 (online)
Significance
Enantioselective radical reactions have attracted interest lately due to their ability to introduce various stable radical intermediates to electrophiles. This paper reports the radical conjugate addition to enones using a 1,4-chelating template as opposed to the more popular 1,5-chelate.