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Synfacts 2011(10): 1070-1070
DOI: 10.1055/s-0030-1261155
DOI: 10.1055/s-0030-1261155
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New York
New Additions to the Triptycene Family
H. Zhang, D. Cao*, W. Liu, H. Jiang, H. Meier*
South China University of Technology and Guangdong Pharmaceutical University, Guangzhou, P. R. of China; University of Mainz, Germany
Further Information
Publication History
Publication Date:
20 September 2011 (online)
Significance
The authors describe the syntheses of heterocyclic homotriptycene scaffolds via carbocation chemistry. The precursors were synthesized by an efficient alkylation-reduction sequence to afford the alcohol compounds which subsequently rearranged to the heterocyclic homotriptycene frameworks in the presence of acid.