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Synthesis 2004(15): 2419-2440
DOI: 10.1055/s-2004-831223
DOI: 10.1055/s-2004-831223
REVIEW
© Georg Thieme Verlag Stuttgart · New York
Palladium Catalysts for the Suzuki Cross-Coupling Reaction: An Overview of Recent Advances
Further Information
Received
28 May 2004
Publication Date:
16 September 2004 (online)
Publication History
Publication Date:
16 September 2004 (online)
Abstract
This review with 206 references covers the literature published until March 2004 on the development and applications of new efficient catalyst systems for the Suzuki palladium-catalysed cross-coupling reaction of organoboron compounds with organic electrophiles. Where possible, the relative advantages of the new catalyst systems in this synthetically very important carbon-carbon bond forming reaction have been compared.
1 Introduction
2 Palladacycle Complexes as Catalyst Precursors
3 Catalyst Systems Composed of Pd(0) or Pd(II) Derivatives and Electron-Rich and/or Bulky Phosphine Ligands
4 Catalyst Systems Composed of Pd(0) or Pd(II) Derivatives and N-Heterocyclic Carbene Ligands
5 Water-Soluble Catalyst Precursors
6 Ligandless Catalyst Precursors
7 Other Novel Pd Catalyst Precursors
8 Conclusions
Key words
palladium - complexes - boron - catalysis - cross-coupling
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