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Synlett 2001; 2001(12): 1878-1880
DOI: 10.1055/s-2001-18756
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C2-Symmetric Bissulfoximines in Palladium-catalyzed Allylic Alkylations

Carsten Bolm* , Oliver Simić, Marc Martin
  • *Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Str. 1, 52056 Aachen, Germany; Fax: + 49(241)8092391; E-mail: Carsten.Bolm@oc.RWTH-Aachen.de
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Publication Date:
04 December 2001 (online)

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C2-Symmetric bissulfoximines 2 have been used as chiral ligands in palladium-catalyzed asymmetric allylic alkylations. With 2c enantioselectivities of up to 98% ee have been achieved in the reaction of 1,3-diphenylpropenyl acetate with malonates as nucleophiles.

asymmetric catalysis - allylic alkylation - enantioselectivity - palladium - sulfoximines

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