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Synlett 2001; 2001(9): 1476-1478
DOI: 10.1055/s-2001-16806
DOI: 10.1055/s-2001-16806
letter
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Efficient Synthesis of EDO-S,S-DMEDT-TTF, a Potent Organic-Donor for Synthetic Metals
Further Information
Publication History
Publication Date:
28 August 2001 (online)
Optically active ethylenedioxy-S,S-dimethylethylenedithiotetrathiafulvalene (EDO-S,S-DMEDT-TTF: 1) has been synthesized in satisfactory yield using a triethyl phosphite-mediated cross-coupling of (5S,6S)-5,6-dimethyl-1,3-dithiolane-2-one 4 with unsubstituted 1,3-dithiolane-2-thione 6.
organic-donor - EDO-DMEDT-TTF - 1,3-dithiolane-2-thione - cross-coupling