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Synlett 2001; 2001(9): 1470-1472
DOI: 10.1055/s-2001-16805
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Rhodium-Catalyzed Conjugated Addition of Aryllead Reagents to α,β-Unsaturated Carbonyl Compounds in Air and Water

Rui Ding* , Yong-Jun Chen, Dong Wang, Chao-Jun Li
  • *Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, P.R. China
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Publication Date:
28 August 2001 (online)

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In the presence of a rhodium catalyst, α,β-unsaturated esters and ketones (1a-f) react with phenyltrimethyllead 2 in aqueous media and under an air atmosphere to give the corresponding conjugated addition products (3a-e) in high yields.

rhodium catalyst - phenyltrimethyllead - conjugated addition - aqueous media

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