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Synlett 2000; 2000(11): 1628-1630
DOI: 10.1055/s-2000-7933
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Nickel-Catalysed Synthesis of C-Glycosides and Deoxysugars from Glycosyl Bromides

S. Kristy Readman* , Stephen P. Marsden, Anne Hodgson
  • *Department of Chemistry, Imperial College of Science, Technology and Medicine, London SW7 2AY, UK; E-mail: s.marsden@ic.ac.uk
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Publication Date:
31 December 2000 (online)

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A radical-based synthesis of C-glycosides from glycosyl bromides is reported, in which the traditional tin hydride methods are replaced by the use of a nickel (II) salt and manganese dust. The reactions are operationally simpler and in many cases higher yielding than competing methods.

C-glycosides - nickel - catalysis - radicals - glycosyl bromides

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