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Synlett 2000; 2000(9): 1351-1353
DOI: 10.1055/s-2000-7144
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One-Pot Conversion of Oximes to N-(tert-Butoxycarbonyl) Amines with Polymethylhydrosiloxane, Pd-C and Di-tert-butyl Dicarbonate

S. Chandrasekhar* , M. Venkat Reddy, L. Chandraiah
  • *Indian Institute of Chemical Technology, Hyderabad 500 007, India; Fax +91 40 7 17 33 87; E-mail: srivaric@iict.ap.nic.in
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Publication History

Publication Date:
31 December 2000 (online)

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N-(tert-butoxycarbonyl) amines are directly obtained from oximes of aldehydes and ketones in one-pot when treated with polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate in the presence of catalytic amount of 10% Pd-C for the first time.

polymethylhydrosiloxane - oximes - tert-butylcarbamates - one-pot reaction

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