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Synlett 2000; 2000(7): 1022-1024
DOI: 10.1055/s-2000-6673
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Copper-Catalyzed N-Arylation of Amines with Hypervalent Iodonium Salts

Suk-Ku Kang* , Sang-Ho Lee, Duckhee Lee
  • *Department of Chemistry, Sungkyunkwan University, Natural Science Campus, Suwon 440-746, Korea
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Publication Date:
31 December 2000 (online)

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The copper-catalyzed N-arylation of amines with hypervalent iodonium compounds with secondary aliphatic amines, aromatic amines, azoles and amides was accomplished with catalytic CuI (10 mol%) or Cu(acac)2 (5 mol%) in the presence of Na2CO3 or K2CO3 as a base in CH2Cl2 or toluene under mild conditions.

amination - hypervalent iodonium salts

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