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Synlett 2000; 2000(5): 0587-0590
DOI: 10.1055/s-2000-6641
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Heteroconjugate Addition Strategy for the Synthesis of the (HIJ)K-Ring Fragment of Ciguatoxin

Tong-Zhu Liu* , Bettina Kirschbaum, Minoru Isobe
  • *Laboratory of Organic Chemistry, Graduate School of Bioagricultural Sciences, Nagoya University, Chikusa, Nagoya 464-8601, Japan; Fax + 81-52-789-4111; E-mail: isobem@agr.nagoya-u.ac.jp
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Publication Date:
31 December 2000 (online)

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An efficient strategy for the synthesis of the (HIJ)K-ring system of ciguatoxin has been established based on a combination strategy of a heteroconjugate addition reaction and a cobalt complex-mediated cyclization.

ciguatoxin - biscobalthexacarbonyl complex - oxepane cyclization - heteroconjugate addition

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