Download PDF
Synlett 1997; 1997(1): 85-87
DOI: 10.1055/s-1997-720
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Addition Reaction of Allylic Stannanes to the Triplet Excited State of C60 via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid

Koichi Mikami1 , Shoji Matsumoto, Takayuki Tonoi, Tomoyoshi Suenobu2 , Akito Ishida2 , Shunichi Fukuzumi2
  • 1Department of Chemical Technology, Tokyo Institute of Technology, Meguro-ku, Tokyo 152, Japan
  • 2Department of Applied Chemistry, Faculty of Engineering, The Institute of Scientific and Industrial Research, Osaka University, Suita, Osaka 565, Japan
Further Information

Publication History

Publication Date:
22 March 2004 (online)

  PDF Download  Permissions and Reprints All articles of this category

Addition of allylic stannanes to C60 takes place under UV-irradiation in benzene as well as benzonitrile to yield the allylic fullerenes, of which the asymmetric version with pinene-derived chiral allylic stannane leads to an enantio-pure fullerene terpenoid.

fullerene - allylic stannane - photoinduced electron transfer - asymmetric hybridization - chiral fullerene terpenoid

      >