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Synlett 1997; 1997(5): 557-560
DOI: 10.1055/s-1997-3206
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Effects of Fluorine in the Self-assembly of Tetrathiafulvalene-based [3]Catenanes-(circum TTF) - A New Approach to Controlling the Regio- and Configurational Selectivity

Zhan-Ting Li, Jan Becher*
  • *Department of Chemistry, Odense University, Campusvej 55, DK-5230 Odense M, Denmark, Telefax: Int. code +45 66 15 87 80
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Publication Date:
31 December 2000 (online)

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Introduction of fluorine atoms into the macrocyclic acceptor unit leads to significant changes of the regio- and configurational selectivity in the self-assembly of TTF based [3]catenanes-(circum TTF), which are attributed to the donor-acceptor interaction between naphthalene and tetrafluorophenylene units.

fluorine effects - tetrathiafulvalene - catenanes - self-assembly - selectivity

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