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Synlett 1997; 1997(12): 1467-1468
DOI: 10.1055/s-1997-1044
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Approach to Carbocyclic 4-Deoxypyrazofurin through Asymmetrisation of a meso-Norbornene Derivative

Barbara Mohar, JoŽe Kobe1 , Gerrit-Jan Koomen2
  • 1National Institute of Chemistry, Hajdrihova 19, 1115 Ljubljana, Slovenia, Fax 386 61 1259 244; joze.kobe@ki.si
  • 2University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands, Fax 31 20 5255670; gjk@org.chem.uva.nl
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Publication History

Publication Date:
31 December 2000 (online)

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The first enantioselective synthesis of carbocyclic 4-deoxypyrazofurin 1a has been accomplished via (+)-4 which was prepared by asymmetric hydroboration or hydrosilylation reactions.

asymmetric hydrosilylation - asymmetric hydroboration - norbornanes - carbocyclic 4-deoxypyrazofurin

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