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Synlett 1995; 1995(12): 1245-1246
DOI: 10.1055/s-1995-5260
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Enantioselective Allylic Oxidation Using Biomimetic Tris(oxazolines)-Copper(II) Complex

Kenichi Kawasaki, Shigenobu Tsumura, Tsutomu Katsuki*
  • *Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, Fukuoka 812-81, Japan
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Publication Date:
31 December 2000 (online)

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Optically active tris(oxazolines) ligand (1a) was synthesized for the construction of a model compound of the active site of non-heme oxygenase and its copper complex was found to be an efficient catalyst for enantioselective allylic oxidation of cycloalkenes.

allylic oxidation - tris(oxazolines) ligand - tris(oxazolines)-copper(II) complex

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