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Synlett 1995; 1995(7): 711-713
DOI: 10.1055/s-1995-5077
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π-Facial Selectivities of Nucleophilic Addition to Allenecarboxylates1

Yuji Naruse* , Shizuko Kakita, Ayako Tsunekawa
  • *Department of Chemistry, Gifu University, 1-1 Yanagido, GIFU 501-11, JAPAN, Fax +81 58 230 1893; Bitnet naruse@apchem.gifu-u.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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π-Facial selectivities in Michael addition to disubstituted allenecarboxylates give predominantly syn-product with Et2NH and PhSLi-PhSH and exclusively anti with LAH-AlCl3 as the nucleophile.

π-facial selectivities - nucleophilic addition - allenecarboxylates

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