Substitution of Arylsulfonyl Imidazolides by Hydrogen Peroxide: Aryl Sulfonic  Peracids as Oxidants for Olefins

Manfred Schulz; Ralph Kluge; Mareike Lipke

doi:10.1055/s-1993-22651

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Synlett 1993; 1993(12): 915-918
DOI: 10.1055/s-1993-22651

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Substitution of Arylsulfonyl Imidazolides by Hydrogen Peroxide: Aryl Sulfonic Peracids as Oxidants for Olefins

Manfred Schulz^* , Ralph Kluge, Mareike Lipke

^*Department of Chemistry, Martin-Luther-University Halle-Wittenberg, D-06217 Merseburg, Germany

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Publication Date:
19 March 2002 (online)

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Aryl sulfonic peracids were generated in situ by reaction of corresponding arylsulfonyl imidazolides with H₂O₂ in alkaline medium.

The former were compared with other epoxidation agents with a variety of olefins. Compared to the arylsulfonyl chloride / KO₂ system, aryl sulfonic peracids showed different reactivity and selectivity towards olefins.

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