Synlett 1993; 1993(9): 705-707
DOI: 10.1055/s-1993-22580
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Elaboration of 3,4-Dihydro-2H-pyran via η2(3-Oxacyclohexyne)-Zirconocene

Michael C. J. Harris* , Richard J. Whitby, Julian Blagg
  • *Chemistry Department, The University, Southampton SO9 5NH, England
Further Information

Publication History

Publication Date:
19 March 2002 (online)

β-hydrogen activation via loss of methane from 6-(zirconocene(methyl))-3,4-dihydro-2H-pyran affords η2-(3-oxacyclohexyne)-zirconocene which inserts unactivated alkenes and alkynes to afford elaborated dihydropyrans on aqueous work-up.

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