Asymmetric Dihydroxylation of α-Substituted Styrene Derivatives

Zhi-Min Wang; K. Barry Sharpless

doi:10.1055/s-1993-22547

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Synlett 1993; 1993(8): 603-604
DOI: 10.1055/s-1993-22547

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Asymmetric Dihydroxylation of α-Substituted Styrene Derivatives

Zhi-Min Wang^* , K. Barry Sharpless

^*Department of Chemistry, The Scripps Research Institute, 10666 N. Torrey Pines Road, La Jolla, California 92037, USA

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Publication Date:
19 March 2002 (online)

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Asymmetric dihydroxylation of 2-aryl acrylate and 2-phenyl allyl alcohol derivatives was studied using the new ligand(DHQD)₂-PHAL. Diols with good to excellent optical purity were obtained from 2a, 2b, 3a, 3b and 3e.

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