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Synlett 1991; 1991(8): 561-562
DOI: 10.1055/s-1991-20797
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Chiral (Acyloxy)borane Catalyzed Asymmetric Allylation of Aldehydes

Kyoji Furuta* , Makoto Mouri, Hisashi Yamamoto
  • *Department of Applied Chemistry, Nagoya University, Chikusa, Nagoya 464-01, Japan
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Publication Date:
07 March 2002 (online)

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Chiral (acyloxy)borane, obtained from (2R, 3R)-2-O-(2,6-diisopropoxybenzoyl)tartaric acid and tetrahydrofuranborane complex, catalyzes the allylation of achiral aldehydes with allylsilanes to afford homoallylic alcohols with high enantiomeric excess. The reactions proceed in a catalytic manner.

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