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Synlett 1990; 1990(5): 253-255
DOI: 10.1055/s-1990-21052
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Enantiomerically Pure N-Boc Protected β-Keto-γ-Amino Acid Esters from Simple Keto Precursors: A Novel, Stereocontrolled Approach to Statine Derivatives with Any Desired Configuration1

Gerhard Bringmann* , Georg Künkel, Torsten Geuder
  • *Institute of Organic Chemistry, University of Würzburg, Am Hubland, D-8700 Würzburg, Federal Republic of Germany
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Publication Date:
08 March 2002 (online)

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A simple, short, and chiral-pool-independent method for the preparation of enantiomerically pure statine precursors is described, using 1-phenylethylamine as an inexpensive chiral auxiliary, commercially available in both enantiomeric forms.