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Synlett 1990; 1990(4): 221-223
DOI: 10.1055/s-1990-21043
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Palladium-Catalyzed Cross-Coupling Reaction of Aryl or Vinylic Triflates with Organoboron Compounds

Takayuki Oh-e* , Norio Miyaura, Akira Suzuki
  • *Department of Applied Chemistry, Faculty of Engineering, Hokkaido University, Sapporo 060, Japan
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Publication Date:
08 March 2002 (online)

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The palladium-catalyzed coupling reactions of aryl or 1-alkenyl triflates with alkyl-, aryl-, and 1-alkenylboron compounds in the presence of potassium phosphate take place readily in high yield under mild conditions. The reaction provides a simple method for the preparation of alkenes, 1,3-alkadienes, aryl-alkenes, and biaryls.

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