Download PDF
Synthesis 1989; 1989(1): 45-47
DOI: 10.1055/s-1989-27145
communication
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Catalytic Hydroxylation of Olefins by Polymer-Bound Osmium Tetroxide

Gianfranco Cainelli* , Michele Contento, Francesco Manescalchi, Laura Plessi
  • *Dipartimento di Chimica "G. Ciamician", Università degli Studi di Bologna, Via F. Selmi 2, I-40126 Bologna, Italy
Further Information

Publication History

Publication Date:
27 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Osmium tetroxide, linked to insoluble crosslinked polymers and copolymers bearing tertiary amino functions, has been used in the presence of secondary oxidants, such as hydrogen peroxide, tert-butyl hydroperoxide and trimethylamine N-oxide, to accomplish the catalytic hydroxylation of olefins. The polymeric reagent offers the advantages of easy and safe handling, and simple separation from the reaction medium. Generally good yields of vicinal diols have been obtained.

      >