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Synlett 2024; 35(08): 851-861
DOI: 10.1055/s-0042-1751519
DOI: 10.1055/s-0042-1751519
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Special Issue dedicated to Keith Fagnou
Nickel-Catalyzed sp3 C–H Activation
We thank the University of Toronto (UofT), the Natural Science and Engineering Research Council (NSERC), Alphora Research Inc. and Kennarshore Inc. for financial support. C. E. J. thanks the Ontario government for an OGS fellowship. R. A. thanks NSERC for a CGS-D fellowship. B. M. thanks NSERC for a CGS-D fellowship.
Abstract
Base metal catalyzed C–H activation represents a highly atom economic method to access functionalized molecules. This Account will focus on Ni-catalyzed C–H activation of sp3-hybridized carbon atoms with a particular focus on mechanism, recent applications, challenges, and outlook in this area. This Account will primarily focus on recent mechanistic work from 2017–2023.
1 Base Metal C–H Activation
2 Nickel-Catalyzed sp3 C–H activation
3 Differences between Ni and Pd
4 Mechanistic Considerations
5 Elementary Steps
6 Directed sp3 C–H Activation
7 Choice of Directing Group
8 Primary C–H Activation
9 Secondary C–H Activation
10 Tertiary C–H Activation
11 Conclusion and Outlook
Publication History
Received: 06 September 2023
Accepted after revision: 04 October 2023
Article published online:
24 November 2023
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