Synlett 2024; 35(13): 1465-1470
DOI: 10.1055/s-0042-1751514
synpacts

Construction of Bibenzothiophenes through Oxidative C–H Cyclization with 1,3-Diynes

Jingyi Chen
,
Tao Lei
,
Danyang Wan
,
Yudong Yang
This work was supported by grants from the National Natural Science Foundation of China (22171188), the Natural Science Foundation of Sichuan Province (2022NSFSC0295) and the Fundamental Research Funds for the Central Universities.


Abstract

The development of concise and efficient methods to construct bithiophene derivatives is an appealing task in the fields of organic chemistry and organic functional materials. Herein, we summarize our recent efforts towards the development of catalytic oxidative C–H cyclization reactions of thiophenol derivatives with 1,3-diynes, which provides a straightforward and effective synthetic approach to both symmetrical and nonsymmetrical 3,3′-bibenzothiophenes. This work is expected to stimulate the application of catalytic oxidative C–H annulation of aromatics with 1,3-diynes for the exploitation of organic functional materials.



Publication History

Received: 07 September 2023

Accepted after revision: 21 September 2023

Article published online:
31 October 2023

© 2023. Thieme. All rights reserved

Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany

 
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