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DOI: 10.1055/s-0031-1289641
Development of Noncovalent Supported Ionic Liquid Phase Catalyst (SILPC) for Liquid-Phase Reaction as a Benign and Sustainable Protocol to Immobilize Homogeneous Catalyst
Publication History
Received: 22 August 2011
Publication Date:
09 February 2012 (online)
Abstract
Homogeneous catalysts were immobilized to the pores of amorphous inorganic supports with the aid of an ionic liquid as Pd-, Cu-, and Ru-supported ionic liquid phase catalyst (SILPC), which is a benign method to immobilize sophisticated but unstable homogeneous catalysts so far difficult to load in an inorganic support by simple impregnation method. By immobilizing as a SILPC, sustainability and reactivity of catalysts increased in Mizoroki–Heck reaction, Suzuki–Miyaura reaction, Huisgen [3+2] cycloaddition (click reaction) without external ligand in aqueous media and ambient atmosphere, and olefin metathesis reactions. In addition, palladium was immobilized on nano-silica gel dendrimer as a nano-SILPC, which was highly active to Suzuki–Miyaura reaction. Moreover, MacMillan imidazolidinone organomolecular catalyst was immobilized as a Mac-SILPC to enable sustainable asymmetric Diels–Alder reaction. SILPCs could be repeatedly used by filtration.
1 Introduction
2 Recyclable Mizoroki–Heck Reaction in an Ionic Liquid Catalyzed by Pd/C
3 Immobilization of Pd in an Amorphous Inorganic Oxide with the Aid of an Ionic Liquid – Preparation of Pd-SILPC
4 Mizoroki–Heck Reaction Catalyzed by Pd-SILPC
5 Mizoroki–Heck Reaction in Water Catalyzed by Pd-SILPC
6 Suzuki–Miyaura Reaction Catalyzed by Pd-SILPC
7 Immobilization of Pd in Nano-Silica Gel Dendrimer as Pd-Nano-SILPC and Suzuki–Miyaura Reaction
8 Polymer-Coated Pd-SILPC and Suzuki–Miyaura Reaction
9 Catalytic Hydrogenation Catalyzed by Pd-SH-SILPC
10 Immobilization of Cu as Cu-SILPC and Huisgen [3+2] Cycloaddition
11 Immobilization of Grubbs Catalyst as Ru-SILPC and Olefin Metathesis Reaction
12 Immobilization of MacMillan Organocatalyst as Mac-SILPC and Asymmetric Diels–Alder Reaction
13 Conclusions
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