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Synthesis 2010(22): 3873-3878  
DOI: 10.1055/s-0030-1258255
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of 3-Substituted Derivatives of 2,2,6,6-Tetramethylpiperidine-N-alkoxyamine Ethers: Novel Alkoxyamine Building Blocks

Walter Fischera, Abdel-Ilah Basbasa, Kai-Uwe Schoening*a, Stefan Hauck*b
a BASF Schweiz AG, 4002 Basel, Switzerland
Fax: +41(61)6362115; e-Mail: kai-uwe.schoening@basf.com;
b Galata Chemicals GmbH, 68623 Lampertheim, Germany
Further Information

Publication History

Received 17 July 2010
Publication Date:
15 September 2010 (online)

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Abstract

The Michael addition of 4-oxo-TMP-alkoxyamine-derived­ Schiff bases to acrylates provides a convenient way to obtain a variety of novel and versatile alkoxyamine building blocks.

Key words

N-alkoxyamines - radical reaction - piperidines - peroxides - TEMPO derivatives

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