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Synthesis 2010(9): 1493-1499
DOI: 10.1055/s-0029-1218693
DOI: 10.1055/s-0029-1218693
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Chemoselective (Trans)thioacetalization of Carbonyl Compounds with a Reusable Lewis Acid-Surfactant-Combined Copper Bis(dodecyl sulfate) Catalyst in Water
Further Information
Received
8 December 2009
Publication Date:
09 March 2010 (online)
Publication History
Publication Date:
09 March 2010 (online)
Abstract
A Lewis acid-surfactant-combined copper bis(dodecyl sulfate) [Cu(DS)2] catalyst served as an efficient and reusable catalyst for the thioacetalization and transthioacetalization of carbonyl compounds and O,O-acetals in water at room temperature. Some of the major advantages of this procedure are high chemoselectivity, ease of operation and purification without any organic solvent, and high yields.
Key words
thioacetalization - transthioacetalization - Lewis acid-surfactant-combined catalysts - copper bis(dodecyl sulfate) - reusability
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