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Synfacts 2010(1): 0124-0124  
DOI: 10.1055/s-0029-1218452
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

C-N/C-O Bond Formation with CuI Nanoparticles

Contributor(s): Yasuhiro Uozumi, Tsubasa Muto
B. Sreedhar*, R. Arundhathi, P. L. Reddy, M. L. Kantam
Indian Institute of Chemical Technology, Hyderabad, India
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Publication History

Publication Date:
21 December 2009 (online)

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Significance

Copper iodine nanoparticles prepared by a sodium citrate assisted hydrothermal method catalyzed the cross-coupling reactions of chlorobenzenes 1 and various N- and O-nucleophiles 2 and 4 to give the corresponding products 3 (25 examples) and 5 (16 examples), respectively, in up to 99% yield.