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Synthesis 2009(19): 3285-3292
DOI: 10.1055/s-0029-1216953
DOI: 10.1055/s-0029-1216953
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Total Synthesis of (+)-Dodoneine and Its 6-Epimer
Further Information
Received
20 March 2009
Publication Date:
21 August 2009 (online)
Publication History
Publication Date:
21 August 2009 (online)
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Abstract
The total synthesis of dodoneine and its 6-epimer is described, using HKR of epoxide and reduction with SmI2 reactions as key steps, respectively.
Key words
dodoneine - epidodoneine - trimethylsulfonium iodide - HKR - SmI2 - RCM
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