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Synthesis
DOI: 10.1055/a-2312-5815
DOI: 10.1055/a-2312-5815
paper
Special Issue Dual Catalysis
Tandem One-Pot Synthesis of 2H- and 3H-Pyrroles Enabled by Dual Rh(II)/Pd(0) Catalysis
This work was financially supported by National Research Foundation (2022R1A2C1002829). This work was supported by the Dongguk University Research Fund of 2024.
Abstract
Regioselective approaches toward 2H- and 3H-pyrroles, which are biologically important but easily isomerizable compounds, have been successfully achieved via dual Rh(II)/Pd(0) relay catalysis and DBU-mediated processes in one-pot operation using N-tosyltriazoles and hydroxymethylallyl carbonates. In this transformation, readily accessible N-tosyltriazoles were enabled as stable nitrogen sources for the two scaffolds, and the regioselectivity was controlled by the substituent positions of the hydroxymethylallyl carbonates.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2312-5815.
- Supporting Information
Publication History
Received: 06 March 2024
Accepted after revision: 23 April 2024
Accepted Manuscript online:
23 April 2024
Article published online:
06 May 2024
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