Synthesis 2024; 56(11): 1687-1694
DOI: 10.1055/a-2200-5332
feature
New Trends in Organic Synthesis from Chinese Chemists

Electrochemical Hydro- and Deuterocarboxylation of Allenes

Cheng-Lin Ding
,
Jun-Song Zhong
,
Hong Yan
,
Ke-Yin Ye
Financial support from the National Natural Science Foundation of China (No. 22171046), Hundred-Talent Project of Fujian (No. 50021113), and Fuzhou University (No. 510841) is gratefully acknowledged.


Abstract

Electrochemical hydrocarboxylation and deuterocarboxylation of allenes and carbon dioxide were achieved with H2O and D2O, respectively. This reaction generally affords good to excellent regioselectivity in the formation of diverse carboxylic acids.

Supporting Information



Publikationsverlauf

Eingereicht: 14. September 2023

Angenommen nach Revision: 27. Oktober 2023

Accepted Manuscript online:
27. Oktober 2023

Artikel online veröffentlicht:
27. November 2023

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