Synthesis 2003(13): 2001-2004
DOI: 10.1055/s-2003-41021
PAPER
© Georg Thieme Verlag Stuttgart · New York

Reduction of Nitroarenes to Aromatic Amines with Nanosized Activated Metallic Iron Powder in Water

Lei Wang*a,b, Pinhua Lia, Zongtao Wua, Jincan Yana, Min Wanga, Yanbin Dinga
a Department of Chemistry, Huaibei Coal Teachers College, Huaibei, Anhui 235000, P. R. China
Fax: +86(561)3090518; e-Mail: leiwang@hbcnc.edu.cn;
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China
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Publikationsverlauf

Received 8 May 2003
Publikationsdatum:
19. August 2003 (online)

Abstract

A practical reduction of nitroarenes with nanosized activated metallic iron powder in water at 210 °C (near-critical water) has been developed. The reduction generates the corresponding aromatic amines in excellent yields.