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Synthesis 2024; 56(17): 2614-2626
DOI: 10.1055/s-0042-1751575
DOI: 10.1055/s-0042-1751575
short review
Stereospecific Palladium-Catalyzed Cross-Coupling of Alkylboron Compounds: A Short Account
This work was supported by the Creative-Pioneering Researchers Program, Seoul National University.
Abstract
Stereospecific approaches allow the introduction of a stereogenic center into complex organic molecules using optically active reagents. Among these, the Pd-catalyzed stereospecific cross-coupling of chiral alkylboron compounds stands out as a highly effective tool for organic synthesis. In parallel with advances in the development of borylation technology, the strategy has recently witnessed a growth in its applicability. This account aims to review the progress on Pd-catalyzed stereospecific B-alkyl Suzuki–Miyaura cross-coupling, tracing its evolution from early breakthroughs to the most recent advances.
1 Introduction
2 Cross-Coupling of 1° Alkylboron Compounds
3 Cross-Coupling of Benzylboron Compounds
4 Cross-Coupling of Allyl- and Propargylboron Compounds
5 Cross-Coupling of Other Types of Activated 2° Alkylboron Compounds
6 Cross-Coupling of Unactivated 2° Alkylboron Compounds
7 Conclusion and Outlook
Publication History
Received: 22 January 2024
Accepted after revision: 04 March 2024
Article published online:
20 March 2024
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For representative reviews, see:
For representative reviews on borylation, see: