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Synlett 2017; 28(07): 835-840
DOI: 10.1055/s-0036-1588930
DOI: 10.1055/s-0036-1588930
letter
Ligandless Palladium-Catalyzed Reductive Carbonylation of Aryl Iodides under Ambient Conditions
Further Information
Publication History
Received: 26 October 2016
Accepted after revision: 13 December 2016
Publication Date:
12 January 2017 (online)


Abstract
Ligandless palladium-catalyzed reductive carbonylation of aryl iodides for the synthesis of aromatic aldehydes has been developed. This carbonylation process proceeded effectively even under ambient temperature and pressure. In addition, this method enables successive reductive carbonylation of diiodobenzenes to furnish dialdehydes in satisfactory yields. Finally, the nature of the active catalytic species is discussed.
Key words
aromatic aldehydes - aryl iodides - reductive carbonylation - ligandless - ambient conditionsSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0036-1588930.
- Supporting Information