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Synlett 2016; 27(14): 2095-2100
DOI: 10.1055/s-0035-1561480
DOI: 10.1055/s-0035-1561480
cluster
Synthesis of Unexpected trans-meso Macrocycle from Novel Unsymmetrical Tetraphenylene
Weitere Informationen
Publikationsverlauf
Received: 03. Mai 2016
Accepted after revision: 21. Mai 2016
Publikationsdatum:
23. Juni 2016 (online)


Abstract
A highly unsymmetrical trisubstituted tetraphenylene was designed and synthesized as a novel superamolecular scaffold for an unexpected trans-meso tetraphenylene macrocycle, whose structure was unequivocally characterized by an X-ray crystallographic analysis. With the defined and electron-rich aromatic cavity, this macrocycle could be further modified to be a potential host for organic cations with biological interest.
Key words
tetraphenylene - nonplanar hydrocarbon - macrocycle - host-guest chemistry - cation π interactionsSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561480.
- Supporting Information