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Synlett 2015; 26(09): 1179-1184
DOI: 10.1055/s-0034-1380196
DOI: 10.1055/s-0034-1380196
letter
A Simple Procedure for the Oxidation of Alcohols Using [Bis(acetoxy)iodo]benzene and a Catalytic Amount of Bromide Ions in Ethyl Acetate
Further Information
Publication History
Received: 17 February 2015
Accepted after revision: 09 March 2015
Publication Date:
16 April 2015 (online)
![](https://www.thieme-connect.de/media/synlett/201509/lookinside/thumbnails/st-2015-b0109-l_10-1055_s-0034-1380196-1.jpg)
Abstract
Primary and secondary benzylic alcohols and secondary aliphatic alcohols were oxidized to the corresponding aldehydes and ketones by using [bis(acetoxy)iodo]benzene (BAIB) and a catalytic amount of bromide ions, from tetrabutylammonium bromide or KBr, in ethyl acetate. The catalytic role of the bromide ions was also highlighted in the oxidation of primary aliphatic alcohols and secondary allylic alcohols carried out in the presence of 1 mol% TEMPO.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380196.
- Supporting Information
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