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Synlett 2015; 26(17): 2332-2335
DOI: 10.1055/s-0034-1378789
DOI: 10.1055/s-0034-1378789
synpacts
Catalytic Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes
Further Information
Publication History
Received: 17 May 2015
Accepted after revision: 16 June 2015
Publication Date:
23 July 2015 (online)
![](https://www.thieme-connect.de/media/synlett/201517/lookinside/thumbnails/st-2015-p0379-sp_10-1055_s-0034-1378789-1.jpg)
Abstract
Catalytic asymmetric hydrosilylation of 1,1-disubstituted alkenes has been summarized. The intramolecular reactions proceed efficiently in the presence of noble transition-metal rhodium. The highly enantioselective intermolecular processes are catalyzed by earth-abundant transition-metal iron.
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For a review on palladium-catalyzed asymmetric hydrosilylation of alkenes, see:
For some samples on palladium-catalyzed hydrosilylation of alkenes, see:
For a review on rhodium-catalyzed asymmetric hydrosilylation of alkenes, see: