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Synthesis 2014; 46(12): 1573-1582
DOI: 10.1055/s-0033-1341224
DOI: 10.1055/s-0033-1341224
short review
Catalytic Enantioselective Desymmetrizations of Prochiral Dienone Systems
Weitere Informationen
Publikationsverlauf
Received: 27. Februar 2014
Accepted after revision: 26. März 2014
Publikationsdatum:
24. April 2014 (online)
Abstract
This article describes a number of catalytic methods for enantioselectively desymmetrizing prochiral dienone systems. The core structures obtained using these methodologies appear in several bioactive natural products, and the processes appear to be effective tools for producing key intermediates in the synthesis of complex structures.
1 Introduction
2 Covalent Organocatalyzed Desymmetrizations
2.1 Formation of Chiral Enamines
2.2 The Stetter Reaction
2.3 Other Covalent Desymmetrizations
3 Noncovalent Organocatalyzed Desymmetrizations
4 Transition Metals
5 Cycloadditions
6 Conclusion
-
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