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Synthesis 2013; 45(8): 1029-1033
DOI: 10.1055/s-0032-1318388
DOI: 10.1055/s-0032-1318388
practical synthetic procedures
A Practical Synthesis of Azobenzenes through Oxidative Dimerization of Aromatic Amines Using tert-Butyl Hypoiodite
Further Information
Publication History
Received: 22 January 2013
Accepted after revision: 15 February 2013
Publication Date:
07 March 2013 (online)
Abstract
A straightforward, convenient, and efficient synthetic method of azobenzenes through oxidative dimerization of aromatic amines using a unique and cost-effective iodinating reagent is described. This new method allows for easy access to both of symmetrical and unsymmetrical azobenzenes under extremely mild conditions.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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Reviews on azobenzene-based soft materials:
Reviews on synthetic methods of aromatic azo compounds:
Selected examples:
Selected examples: