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DOI: 10.1055/s-0031-1289558
The Advance and Application of Rare Earth Perfluorooctanoate [RE(PFO)3]
Publication History
Publication Date:
25 October 2011 (online)
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Abstract
Synthesis and characterization of a new type of Lewis acid, rare earth metal perfluorooctanoate, as well as the recent development of multicomponent condensation reactions catalyzed by rare earth metal perfluorooctanoate has been introduced.
1 Introduction and Background
2 Synthesis and Characterization of Rare Earth Perfluorooctanoate
2.1 Synthesis of Rare Earth Perfluorooctanoate
2.2 Characterization of Rare Earth Perfluorooctanoate
3 RE(PFO)3 in Organic Solvent
3.1 One-Pot Mannich Reaction
3.2 Condensations of Indole with Carbonyl Compounds
3.3 One-Pot Synthesis of Benzopyran Derivatives
3.4 One-Pot Synthesis of 2-Amino-3-Cyanopyridine Derivatives
4 RE(PFO)3 in Water
4.1 Doebner Reaction
4.2 Synthesis of Homoallylic Alcohols and Amines
5 RE(PFO)3 under Solvent-Free Conditions
5.1 Synthesis of α-Aminophosphonates
5.2 One-Pot Synthesis of Substituted Pyrazoles
5.3 A Revisit to the Hantzsch Reaction
5.4 One-Pot Fluorous Biginelli Reaction
6 Summary
Key words
rare earths - perfluorooctanoate - multicomponent condensation reaction - Lewis acids - homogeneous catalysis
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