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Synthesis 2011(1): 154-160
DOI: 10.1055/s-0030-1258324
DOI: 10.1055/s-0030-1258324
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis and Reactivity of β,γ-Dihalogenated Unsaturated Acids: Application to the Synthesis of 4-Substituted 5H-Furan-2-ones
Further Information
Received
14 September 2010
Publication Date:
15 November 2010 (online)
Publication History
Publication Date:
15 November 2010 (online)
Abstract
β,γ-Dihalogenated unsaturated acids were prepared regio- and stereoselectively from allenic acid, and some aspects of their reactivities were studied.
Key words
α,β-unsaturated acids - halogenation - carboxylic acids - cross-coupling - organometallic reagents
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References
Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Center under CCDC Nos. 702136 (compound 2d), 745342 (compound 2c), 745343 (compound 2a), and 785338 (compound 2b). Copies of this information may be obtained free of charge from The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: +44 (1223)336033; e-mail: deposit@ccdc.cam.ac.uk or www.http://www.ccdc.cam.ac.uk].