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Synfacts 2010(4): 0436-0436
DOI: 10.1055/s-0029-1219657
DOI: 10.1055/s-0029-1219657
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Metal-Catalyzed Ring-Opening Hydro-metalation of Alkylidenecyclopropanes
S. Simaan, A. F. G. Goldberg, S. Rosset, I. Marek*
Technion-Israel Institute of Technology, Haifa, Israel; Université de Genève, Switzerland
Further Information
Publication History
Publication Date:
22 March 2010 (online)
Significance
This method allows for the transformation of alkylidenecyclopropanes into useful building blocks with retention of stereochemical integrity. Hydrometalation products are quite useful due to the variety of transformations they can undergo.