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Synlett 2010(3): 383-386
DOI: 10.1055/s-0029-1219174
DOI: 10.1055/s-0029-1219174
LETTER
© Georg Thieme Verlag
Stuttgart ˙ New York
Oxidative Deamination of α-Aminophosphonates and Amines by Zinc Dichromate Trihydrate (ZnCr2O7˙3H2O) under Solvent-Free Conditions at Room Temperature
Further Information
Received
25 August 2009
Publication Date:
08 January 2010 (online)
Publication History
Publication Date:
08 January 2010 (online)
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Abstract
A novel method for the rapid and efficient conversion of a variety of α-aminophosphonates to α-ketophosphonates using ZnCr2O7˙3H2O via oxidative deamination under solvent-free conditions at room temperature is described. This method is also applicable to the rapid and highly selective oxidation of various types of ordinary amines (primary and secondary) to aldehydes and ketones in good to high yields.
Key words
oxidative deamination - α-ketophosphonates - α-hydroxyphosphonates - amines - aldehydes
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