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Synfacts 2009(5): 0543-0543
DOI: 10.1055/s-0028-1088040
DOI: 10.1055/s-0028-1088040
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Fluorination of Aryl Stannanes Mediated by AgOTf
T. Furuya, A. E. Strom, T. Ritter*
Harvard University, Cambridge, USA
Further Information
Publication History
Publication Date:
22 April 2009 (online)
Significance
A highly general procedure for the fluorination of aryl stannanes using Ag(OTf) as mediator was developed. The reaction tolerates a broad spectrum of very sensitive functionalities and is thus applicable in late synthetic stages.