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Synfacts 2008(11): 1209-1209  
DOI: 10.1055/s-0028-1083464
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Dehydrogenative Cyclocondensation of Dialkylsilanes Providing Oxasilacyclopentenes

Contributor(s): Paul Knochel, Tobias Thaler
R. D. Baxter, J. Montgomery*
University of Michigan, Ann Arbor, USA
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Publication History

Publication Date:
23 October 2008 (online)

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Significance

This unprecedented three-component reaction involving diethylsilane as a silylene synthetic equivalent offers a straightforward, re­gioselective access to oxasilacyclopentenes.