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Synlett
DOI: 10.1055/a-2504-3530
DOI: 10.1055/a-2504-3530
synpacts
Cu-Nanoclusters as Emerging Catalyst in Organic Synthesis
Y.N. acknowledge the funding support from the Japan Society for the Promotion of Science (JSPS KAKENHI, grant no. 23H00289, 22K19012, 23KK0098 and 24K01459), the Scientific Research on Innovative Areas ‘Aquatic Functional Materials’ (grant no. 22H04562), the Yazaki Memorial Foundation for Science and Technology, and the Ogasawara Foundation for the Promotion of Science and Engineering. B.S. gratefully thanks the Indian Institute of Science Education and Research (IISER) Thiruvananthapuram for the financial and infrastructural supports. A.P. thanks the MoE, India, for the Prime Minister’s Research Fellowship.
Abstract
In recent decades, nanocluster research has rapidly advanced. Though Cu nanoclusters are relatively new to the field, their use in chemical catalysis has expanded the potential applications of these materials. The reactivity of Cu nanoclusters is primarily determined by their precisely controlled structural architecture and surface-to-volume ratio. However, these factors are prone to change, significantly impacting their catalytic properties. Therefore, a comprehensive understanding of these parameters is crucial to guide future research efforts and develop new Cu nanoclusters with broader applications.
1 Introduction
2 Click Reaction
3 Carbamate Synthesis
4 Ullmann (C–N) Coupling
5 Indolizine Synthesis
6 Hydrogenation Reaction
7 Sonogashira Reaction
8 Hydroboration Reaction
9 Decarboxylative Oxidation of Carboxylic Acids
10 Conclusion
Publication History
Received: 24 October 2024
Accepted after revision: 17 December 2024
Accepted Manuscript online:
17 December 2024
Article published online:
31 January 2025
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References
- 1a Feynman R. There’s Plenty of Room at the Bottom.In Miniaturization. Gilbert HD. Reinhold; New York: 1961. 282
- 1b Biswas S, Das S, Negishi Y. Coord. Chem. Rev. 2023; 492: 215255
- 2 Roduner E. Chem. Soc. Rev. 2006; 35: 583
- 3a Jin R, Zeng C, Zhou M, Chen Y. Chem. Rev. 2016; 116: 10346
- 3b Chakraborty I, Pradeep T. Chem. Rev. 2017; 117: 8208
- 4 Cotton FA. Acc. Chem. Res. 1969; 2: 240
- 5a Du Y, Sheng H, Astruc D, Zhu M. Chem. Rev. 2019; 120: 526
- 5b Sun C, Teo BK, Deng C, Lin J, Luo G.-G, Tung C.-H, Sun D. Coord. Chem. Rev. 2021; 427: 213576
- 5c Hirai H, Ito S, Takano S, Koyasu K, Tsukuda T. Chem. Sci. 2020; 11 12233
- 5d Kang X, Zhu M. Chem. Soc. Rev. 2019; 48: 2422
- 5e Biswas S, Das AK, Mandal S. Acc. Chem. Res. 2023; 3721
- 5f Kawawaki T, Okada T, Hirayama D, Negishi Y. Green Chem. 2024; 26: 122
- 6a Jadzinsky PD, Calero G, Ackerson CJ, Bushnell DA, Kornberg RD. Science 2007; 318: 430
- 6b Desireddy A, Conn BE, Guo J, Yoon B, Barnett RN, Monahan BM, Kirschbaum K, Griffith WP, Whetten RL, Landman U. Nature 2013; 501: 399
- 7 Biswas S, Das S, Negishi Y. Nanoscale Horiz. 2023; 8: 1509
- 8a Biswas S, Negishi Y. J. Phys. Chem. Lett. 2024; 15: 947
- 8b Biswas S, Shingyouchi Y, Ogami M, Kamiyama M, Kawawaki T, Negishi Y. EcoEnergy 2024; 2: 400
- 8c Baghdasaryan A, Bürgi T. Nanoscale 2021; 13: 6283
- 8d Liu Y, Yu J, Lun Y, Wang Y, Wang Y, Song S. Adv. Funct. Mater. 2023; 33: 2304184
- 9 Goeden GV, Caulton KG. J. Am. Chem. Soc. 1981; 103: 7354
- 10 Chen J.-X, Daeuble JF, Brestensky DM, Stryker JM. Tetrahedron 2000; 56: 2153
- 11 Biswas S, Negishi Y. Dalton Trans. 2024; 53: 9657
- 12 Rostovtsev VV, Green LG, Fokin VV, Sharpless KB. Angew. Chem. Int. Ed. 2002; 41: 2596
- 13 Tornøe CW, Christensen C, Meldal M. J. Org. Chem. 2002; 67: 3057
- 14 Makarem A, Berg R, Rominger F, Straub BF. Angew. Chem. Int. Ed. 2015; 54: 7431
- 15 Cook AW, Jones ZR, Wu G, Scott SL, Hayton TW. J. Am. Chem. Soc. 2018; 140: 394
- 16 Dong C, Huang RW, Sagadevan A, Yuan P, Gutiérrez-Arzaluz L, Ghosh A, Nematulloev S, Alamer B, Mohammed OF, Hussain I, Rueping M, Bakr OM. Angew. Chem. Int. Ed. 2023; 62: e202307140
- 17 Zhou H, Yang T, Deng H, Yun Y, Jin S, Xiong L, Zhu M. Nanoscale 2024; 16: 10318
- 18a Ghosh AK, Brindisi M. J. Med. Chem. 2015; 58: 2895
- 18b Matošević A, Bosak A. Arh. Hig. Rada Toksikol. 2020; 71: 285
- 19 Bariwal J, Van der Eycken E. Chem. Soc. Rev. 2013; 42: 9283
- 20 Lee S, Bootharaju MS, Deng G, Malola S, Baek W, Hakkinen H, Zheng N, Hyeon T. J. Am. Chem. Soc. 2020; 142: 13974
- 21 Das AK, Biswas S, Pal A, Manna SS, Sardar A, Mondal PK, Sahoo B, Pathak B, Mandal S. Nanoscale 2024; 16: 3583
- 22a Ćirić-Marjanović G. Synth. Met. 2013; 177: 1
- 22b Vitaku E, Smith DT, Njardarson JT. J. Med. Chem. 2014; 57: 10257
- 22c Ruiz-Castillo P, Buchwald SL. Chem. Rev. 2016; 116: 12564
- 22d Schmidt AW, Reddy KR, Knölker H.-J. Chem. Rev. 2012; 112: 3193
- 23 Sagadevan A, Ghosh A, Maity P, Mohammed OF, Bakr OM, Rueping M. J. Am. Chem. Soc. 2022; 144: 12052
- 24 Wang YM, Lin XC, Mo KM, Xie M, Huang YL, Ning GH, Li D. Angew. Chem. Int. Ed. 2023; 62: e202218369
- 25 Luo GG, Pan ZH, Han BL, Dong GL, Deng CL, Azam M, Tao YW, He J, Sun CF, Sun D. Angew. Chem. Int. Ed. 2023; 62: e202306849
- 26 Liu C.-Y, Liu T.-Y, Guan Z.-J, Wang S, Dong Y.-Y, Hu F, Jiang D.-E-E, Wang QM. CCS Chem. 2024; 6: 1581
- 27 Nematulloev S, Sagadevan A, Alamer B, Shkurenko A, Huang R, Yin J, Dong C, Yuan P, Yorov KE, Karluk AA, Mir WJ, Hasanov BE, Hedhili MN, Halappa NM, Eddaoudi M, Mohammed OF, Rueping M, Bakr OM. Angew. Chem. Int. Ed. 2023; 62: e202303572
- 28 Biswas S, Pal A, Jena MK, Hossain S, Sakai J, Das S, Sahoo B, Pathak B, Negishi Y. J. Am. Chem. Soc. 2024; 146: 20937
- 29a Lennox AJ, Lloyd-Jones GC. Chem. Soc. Rev. 2014; 43: 412
- 29b Takagi J, Takahashi K, Ishiyama T, Miyaura N. J. Am. Chem. Soc. 2002; 124: 8001
- 29c Ishiyama T, Murata M, Miyaura N. J. Org. Chem. 1995; 60: 7508
- 30 West MJ, Fyfe JW, Vantourout JC, Watson AJ. Chem. Rev. 2019; 119: 12491
- 31 Denmark SE, Fu J. Chem. Rev. 2003; 103: 2763
- 32 Nguyen TN, May JA. Tetrahedron Lett. 2017; 58: 1535
- 33 Duret G, Quinlan R, Bisseret P, Blanchard N. Chem. Sci. 2015; 6: 5366
- 34 Alamer B, Sagadevan A, Bodiuzzaman M, Murugesan K, Alsharif S, Huang R.-W, Ghosh A, Naveen MH, Dong C, Nematulloev S, Yin J, Shkurenko A, Abulikemu M, Dong X, Han Y, Eddaoudi M, Rueping M, Bakr OM. J. Am. Chem. Soc. 2024; 146: 16295
- 35 Bodiuzzaman M, Murugesan K, Yuan P, Maity B, Sagadevan A, Malenahalli N, Wang HS, Maity P, Alotaibi MF, Jiang D.-e, Abulikemu M, Mohammed OF, Cavallo L, Rueping M, Bakr OM. J. Am. Chem. Soc. 2024; 146: 26994