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Synfacts 2008(1): 0037-0037
DOI: 10.1055/s-2007-992408
DOI: 10.1055/s-2007-992408
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
Simple Method for Hyperbranched Polymers
I. A. Gorodetskaya, T.-L. Choi, R. H. Grubbs*
California Institute of Technology, Pasadena, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. Dezember 2007 (online)
Significance
Structurally perfect polymer dendrimers have found varied application in medicine, catalysis, and nanofabrication. However, synthesis of such dendrimers is not efficient or economical. Hyperbranched polymers, while not monodisperse, often exhibit similar properties, but recent syntheses require harsh conditions and complex monomers. The authors report a simple preparation of hyperbranched polymers by the mild acyclic diene metathesis (ADMET) reaction using easily prepared monomers.